方向三:固废处理与资源化
Study on Solid Waste Treatment and Resource Utilization
我国固废产量大,且成分复杂、蕴含大量有价金属,其资源化回收与分离纯化成为我国棘手的重大环保问题。本方向针对铜、钨和稀土等江西特色资源及大量废弃锂离子电池,以固废减量化和金属高值化回收为目标,开展尾矿、冶炼废渣/烟尘的无害化、资源化、减量化的新原理、新技术研究,研发冶炼废渣/烟尘无害化、资源化回收技术与装备,取得了理论、方法、工艺和装备的系统创新。发明了价态氧化、三相萃取和外场增强固废中金属浸出效率的新方法,提出了以结晶能力、离子络合和空间匹配调控强化选择性分离能力的新机制,发明了诱导高效除杂技术和分组除杂与多级分馏纯化新技术,发明了印迹空腔选择性吸附分离新技术,开辟了固废中多金属资源化利用的选择性回收模式,实现了金属阴阳离子产品的纯度从2N级到6N级跃升,扭转了纯投入式固废处置模式,开创了固废治理的盈利新途径,中国有色金属工业协会推荐为固废中多金属资源化回收治理最佳可行技术。相关技术成果应用于20多家钨、稀土、废弃锂电池回收等企业,并产生了显著的经济、环境和社会效益,极大的推动了行业的绿色变革。
China has a large amount of solid waste, and its composition is complex, containing a large amount of valuable metals. Its resource recycling, separation and purification have become a major environmental problem in China. With the goal of solid waste reduction and high-value metal recovery, this direction is aimed at Jiangxi's characteristic resources such as copper, tungsten and rare earth, and large quantities of spent lithium-ion batteries. The new principles and technologies for harmless, reduction and resource utilization of tailings, smelting slag/smoke dust are studied, and the technologies and equipment of harmless and resourceful recovery of smelting slag/smoke and dust are developed. The systematic innovation of theory, method, technology and equipment are achieved. A new method of enhancing metal leaching efficiency in solid waste by valence oxidation, three-phase extraction and field is invented, and the mechanism of enhancing selective separation ability by means of crystallization ability, ion complexation and space matching control is proposed. The new technologies of inducing high efficiency impurity removal, grouping impurity removal, multistage fractionation purification and imprinted cavity selective adsorption separation are invented. These technologies opened a selective recycling mode for the utilization of polymetals in solid waste, realized a leap in the purity of metal anions and cations from 2N to 6N, reversed the pure input solid waste disposal mode, and developed a new profitable way for solid waste treatment. It is recommended by China Nonferrous Metals Industry Association as the best feasible technology for multi-metal resource recycling in solid waste. The related technical achievements have been applied to more than 20 enterprises such as tungsten, rare earth and waste lithium battery recycling, and have produced significant economic, environmental and social benefits, which have greatly promoted the green transformation of the industry.